If new parents – again! – Brad Pitt and Angelina Jolie need a night out alone, at least one famous friend has already volunteered to help.

“I’m willing to babysit for them!” Jolie’s pal Wyclef Jean tells PEOPLE in this week’s cover story. The musician, who has partnered with the couple for his Yéle Haiti charity in the past, says he has no doubt they can handle their brood of six now that twins Vivienne Marcheline and Knox Léon are here.

“They will do well,” he says. “I have a lot of well wishes for them.”

So do many of Jolie’s costars, including Michael Kelly, who appears with her in the upcoming Clint Eastwood-directed drama The Changeling.

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Us Weekly magazine has named beautiful couple of Brad Pitt and Angelina Jolie their Couple of the Year. From their charity work to their ever-growing family to their film careers. Coming in right behind Brad and Angelina is Tom Cruise and Kate Holmes.

Click here to view the cover.